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The specific heat capacities of substances comprising molecules (as distinctive from monatomic gases) aren't set constants and change relatively dependant upon temperature.
The discrepancies in heat capacities as outlined by the above mentioned Mayer relation is only actual for a really perfect fuel and might be distinct for virtually any real gas.
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The heat capacity should be zero at zero temperature to ensure that the above mentioned integral to not generate an infinite absolute entropy, which might violate the third law of thermodynamics.
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For liquids and gases, it is necessary to know the strain to which specified heat capability knowledge refer. Most posted info are supplied for normal pressure. Having said that, really distinctive regular problems for temperature and force are actually described by distinct corporations.
Accordingly, the temperature at which the measurement is made is frequently also specified. Examples of two widespread methods to cite the specific heat of the material are as follows:[nine]
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